Heterojunction Band Offset Limitations on Open-Circuit Voltage in <roman>p</roman>-Z<roman>n</roman>T <roman>e/n</roman>-Z<roman>n</roman>S<roman>e</roman> Solar Cells

Effects of Mg composition on open circuit voltage of Cu2O–MgxZn1 xO heterojunction solar cells

MgxZn1 xO (0rxr0.13) films grown by metal-organic chemical vapor deposition (MOCVD) were chosen as the n-type semiconductor layer forming a heterojunction with electrodeposited p-type cuprous oxide (Cu2O) for photovoltaic applications in this study. We investigated the effects of Mg contents (x) on the performance of Ag–Cu2O–MgxZn1 xO–fluorine-doped tin oxide (FTO)-glass heterojunction solar ce...

Relating the open-circuit voltage to interface molecular properties of donor:acceptor bulk heterojunction solar cells

High open circuit voltage organic solar cells based upon fullerene free bulk heterojunction active layers

We have recently reported on a small organic molecule containing a bithiophene core with end-capping phthalimide units (PthTh2Pth) that exhibited a H-aggregation tendency in the solid state and high electron mobility in organic field effect transistors. In this contribution, we have studied both the physical and electrical properties of poly(3-hexylthiophene) (P3HT) and PthTh2Pth thin films by ...

Heterojunction band offset engineering

Control of band discontinuities in semiconductor heterostructures may introduce a new important degree of freedom in the design of heterojunction devices and allow independent optimization of carrier injection, carrier confinement and ionization thresholds in high speed and optoelectronic devices. We will review recently proposed methods to microscopically control heterojunction parameters by m...

Open-Circuit Voltage Physics in Amorphous Silicon Solar Cells

We have performed computer calculations to explore effects of the p/i interface on the opencircuit voltage in a-Si:H based pin solar cells. The principal conclusions are that interface limitation can occur for values of VOC significantly below the built-in potential VBI of a cell, and that the effects can be understood in terms of thermionic emission of electrons from the intrinsic layer into t...